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21.15–21.16 Side-Chain Reactions

21.15 Oxidation of alkyl benzenes

Alkyl groups that are attached to benzene rings can be oxidized with potassium permanganate, KMnO4, or a combination of sodium dichromate, Na2Cr2O7, and H2SO4 to form carboxylic acids. This is a great way to form benzoic acid compounds.

oxidation of alkyl benzene

18. What is the product of the following reaction?

Oxidation of alkyl benzene problem
Answer to oxidation of alkyl benzene problem

21.16 Halogenation of side chains

We have seen previously that benzylic positions are quite reactive to free radical halogenation because the radicals that form are stabilized through resonance.

Bromination of propyl benzene